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Published 17:03 20 Oct 2020 BST
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Van Dijk's absence leaves Liverpool short of options in central defence, and so Klopp will understandably be concerned about Matip.
While Joe Gomez is fit and expected to start the game in Amsterdam, Fabinho is reportedly a candidate to fill in at the back instead of being deployed in his usual role in midfield.
Thiago Alcantara, who was on the receiving end from a red-card challenge from Richarlison on Saturday, was also absent from Tuesday's training session.
He, along with Matip, is a doubt for Wednesday's game and their return to Premier League action against Sheffiled United at the weekend.
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