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17th September 2025
11:57am BST
Liverpool begin their search for a seventh European title by welcoming Atletico Madrid to Anfield, in what promises to be a blockbuster tie on matchday one of the Champions League.
The hosts come into the competition as the favourites, currently sitting at 11/2 with most of the UK's biggest bookmakers, and will want to improve on last year's round-of-16 defeat to eventual champions PSG.
After heavily investing on attacking trio Florian Wirtz, Hugo Ekitike and most recently Alexander Isak in a £125 million deal, there is no doubt Liverpool have the quality to reach the latter stages.
For Atletico Madrid, they arrive in Merseyside having only won once in their opening four games domestically, however, will be full of confidence having finished fifth in the league phase last term.
To raise the stakes even higher for this clash between two European giants, new Betfair users can claim enhanced 50/1 odds for over 0.5 to be scored during Liverpool v Atletico Madrid!
Given it's 640 days since Liverpool last had a 0-0, against Man Utd in December 2023, this is a superb offer.
CLICK HERE to sign up, or read further information below prior to kick-off.
Follow this simple guide to claim Betfair's latest sign up offer for Liverpool v Atletico Madrid and get enhanced 50/1 odds for over 0.5 goals in the match:
Betfair currently has Liverpool and Barcelona as joint favourites to win the competition with odds at 11/2 and an implied probability of 15.4%.
Last season's champions, PSG, are third favourites to retain the trophy and bettors can back Luis Enrique's men at 6/1. Making up the rest of the top five are last year's semi-finalist's Arsenal and record winners Real Madrid, who sit at 13/2 and 15/2 respectively.
| Team | Odds | Implied Probability |
| Liverpool | 11/2 | 15.4% |
| Barcelona | 11/2 | 15.4% |
| PSG | 6/1 | 14.3% |
| Arsenal | 13/2 | 13.3% |
| Real Madrid | 15/2 | 11.8% |
If you are unable to claim the Betfair sign up offer, do not worry as we have listed some popular Champions League betting markets so you can still be involved in Liverpool v Atletico Madrid:
| Liverpool | Odds | Draw | Odds | Atletico Madrid | Odds |
| 2-1 | 15/2 | 1-1 | 8/1 | 2-1 | 18/1 |
| 1-0 | 15/2 | 2-2 | 16/1 | 1-0 | 18/1 |
| 2-0 | 15/2 | 0-0 | 16/1 | 2-0 | 40/1 |
| 3-0 | 10/1 | 3-3 | 70/1 | 3-2 | 50/1 |
| 3-1 | 11/1 | 4-4 | 250/1 | 3-1 | 60/1 |
You can bet on any of the following fixtures for the opening week of the new Champions League season:
Wednesday, 17 September 2025
Thursday, 18 September 2025
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